
The magnetic state (or phase) of a material depends on temperature (and other variables such as pressure and applied magnetic field) so that a material may exhibit more than one form of magnetism depending on its temperature, etc.
In magnetic materials, the most important sources of magnetization are, more specifically, the electrons' orbital angular motion around the nucleus, and the electrons' intrinsic magnetic moment (see Electron magnetic dipole moment). The other potential sources of magnetism are much less important: For example, the nuclear magnetic moments of the nuclei in the material are typically thousands of times smaller than the electrons' magnetic moments, so they are negligible in the context of the magnetization of materials. (Nuclear magnetic moments are important in other contexts, particularly in Nuclear Magnetic Resonance (NMR) and Magnetic Resonance Imaging (MRI).)
Ordinarily, the countless electrons in a material are arranged such that their magnetic moments (both orbital and intrinsic) cancel out. This is due, to some extent, to electrons combining into pairs with opposite intrinsic magnetic moments (as a result of the Pauli exclusion principle; see Electron configuration), or combining into "filled subshells" with zero net orbital motion; in both cases, the electron arrangement is so as to exactly cancel the magnetic moments from each electron. Moreover, even when the electron configuration is such that there are unpaired electrons and/or non-filled subshells, it is often the case that the various electrons in the solid will contribute magnetic moments that point in different, random directions, so that the material will not be magnetic.
However, sometimes (either spontaneously, or owing to an applied external magnetic field) each of the electron magnetic moments will be, on average, lined up. Then the material can produce a net total magnetic field, which can potentially be quite strong.
The magnetic behavior of a material depends on its structure (particularly its electron configuration, for the reasons mentioned above), and also on the temperature (at high temperatures, random thermal motion makes it more difficult for the electrons to maintain alignment).As a consequence of Einstein's theory of special relativity, electricity and magnetism are understood to be fundamentally interlinked. Both magnetism lacking electricity, and electricity without magnetism, are inconsistent with special relativity, due to such effects as length contraction, time dilation, and the fact that the magnetic force is velocity-dependent. However, when both electricity and magnetism are taken into account, the resulting theory (electromagnetism) is fully consistent with special relativity[6].[10] In particular, a phenomenon that appears purely electric to one observer may be purely magnetic to another, or more generally the relative contributions of electricity and magnetism are dependent on the frame of reference. Thus, special relativity "mixes" electricity and magnetism into a single, inseparable phenomenon called electromagnetism (analogous to how relativity "mixes" space and time into spacetime).
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